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5- E ndo - T rig Radical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes

✍ Scribed by Bogen, Stéphane; Gulea, Mihaela; Fensterbank, Louis; Malacria, Max

Book ID
126012926
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
85 KB
Volume
64
Category
Article
ISSN
0022-3263

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ChemInform Abstract: 5-Endo-trig Radical
ChemInform Abstract: 5-Endo-trig Radical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes.
✍ Stephane Bogen; Mihaela Gulea; Louis Fensterbank; Max Malacria 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

5-Endo-trig Radical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes. -The title ethers (I), (V) and (VIII) undergo a radical-induced 5-exo-dig cyclization-diastereoselective 1,5-hydrogen transfer-5-endo-trig