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ChemInform Abstract: (CuI)P4Se4: An Adduct of Polymeric P4Se4 with CuI.

✍ Scribed by Arno Pfitzner; Sara Reiser; Hans-Joerg Deiseroth

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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(CuI)P4Se4: An Adduct of Polymeric P4Se4
(CuI)P4Se4: An Adduct of Polymeric P4Se4 with CuI
✍ Arno Pfitzner; Sara Reiser; Hans-JΓΆrg Deiseroth πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 163 KB

Pure yellow (CuI)P 4 Se 4 was prepared by reaction of stoichiometric amounts of CuI, red P, and gray Se in evacuated silica ampoules. The crystal structure was determined from single crystals at room temperature. (CuI)P 4 Se 4 crystallizes in the orthorhombic system, space group Cmca with a = 14.770

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✍ Sara Reiser; Gunther Brunklaus; Jung Hoon Hong; Jerry C. C. Chan; Hellmut Eckert πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 145 KB πŸ‘ 2 views

(CuI)(3)P(4)S(4) is obtained by reaction of stoichiometric amounts of CuI, P, and S in evacuated silica ampoules. The yellow compound consists of monomeric beta-P(4)S(4) cage molecules that are separated by hexagonal columns of CuI. (CuI)(3)P(4)S(4) crystallizes isotypic to (CuI)(3)P(4)Se(4) in the