(CuBr)3P4Se4: A Low Symmetric Variant of the (CuI)3P4Se4 Structure Type.
β Scribed by Sara Reiser; Tom Nilges; Arno Pfitzner
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 10 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
(CuI)(3)P(4)S(4) is obtained by reaction of stoichiometric amounts of CuI, P, and S in evacuated silica ampoules. The yellow compound consists of monomeric beta-P(4)S(4) cage molecules that are separated by hexagonal columns of CuI. (CuI)(3)P(4)S(4) crystallizes isotypic to (CuI)(3)P(4)Se(4) in the
Ruby-red, bead-shaped single crystals of C-type La 2 Se 3 (a = 905.21(6) pm), Pr 2 Se 3 (a = 891.17(6) pm), and Gd 2 Se 3 (a = 872.56(5) pm) are obtained by oxidation of the respective rare-earth metal (M = La, Pr and Gd) with selenium (molar ratio 2 : 3) in evacuated silica tubes at 750 Β°C in the p
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v