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ChemInform Abstract: Crystal Structure, Ferromagnetic Ordering and Magnetic Anisotropy for Two Cyano-Bridged Bimetallic Compounds of Formula Mn2(H2O)5Mo (CN)7×nH2O.

✍ Scribed by J. LARIONOVA; J. SANCHIZ; S. GOHLEN; L. OUAHAB; O. KAHN

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

1998 structure structure (solids and liquids) D 2000

31 -003

Crystal Structure, Ferromagnetic Ordering and Magnetic Anisotropy for Two Cyano-Bridged Bimetallic Compounds of Formula Mn 2 (H

-Slow diffusion of aqueous solutions containing K 4 [Mo(III)(CN) 7 ]•2H 2 O and Mn(NO 3 ) 2 •6H 2 O affords well shaped single crystals of two cyano-bridged bimetallic phases ordering ferromagnetically with a pronounced magnetic anisotropy in the magnetically-ordered phase. XRD of the α-and β-phases show monoclinic structures (both space group P2 1 /c, Z = 4) in form of elongated plates (α-phase) and prisms (β-phase). All the cyano groups are bridging. Both phases exhibit a long-range magnetic ordering at Tc = 51 K. -(LARIONOVA,

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