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ChemInform Abstract: Structure, Ferromagnetic Ordering, Anisotropy, and Spin Reorientation for the Two-Dimensional Cyano-Bridged Bimetallic Compound K2Mn3(H2O)6 [Mo(CN)7]2×6H2O.

✍ Scribed by Joulia Larionova; Olivier Kahn; Stephane Gohlen; Lahcene Ouahab; Rodolphe Clerac

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Structure, Ferromagnetic Ordering, Anisotropy, and Spin Reorientation for the Two-Dimensional Cyano-Bridged Bimetallic Compound

-Single crystals of the title compound are prepared by slow diffusion of aq. KNO 3 saturated solutions containing K 4 [Mo(CN) 7 ]•2H 2 O and [Mn(H 2 O) 6 ](NO 3 ) 2 , respectively. The compound crystallizes in the monoclinic space group C2 with Z = 4. The Mo site is surrounded by six -C-N-Mn linkages and one terminal cyano group in a strongly distorted pentagonal bipyramid fashion. There are two distorted octahedral Mn sites, both with four -N-C-Mo linkages and two water molecules in trans conformation. The structure is two-dimensional with anionic layers perpendicular to the a axis and K + ions located between the layers. The compound orders ferromagnetically at Tc= 39 K. -(LARIONOVA, JOULIA;

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