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ChemInform Abstract: Copper-Catalyzed Trifluoromethylation of Terminal Alkenes Through Allylic C—H Bond Activation.

✍ Scribed by Jun Xu; Yao Fu; Dong-Fen Luo; Yuan-Ye Jiang; Bin Xiao; Zhao-Jing Liu; Tian-Jun Gong; Lei Liu

Publisher: John Wiley and Sons
Year: 2012
Weight: 31 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201212034

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✦ Synopsis

Abstract

The present new type of Cu‐catalyzed trifluoromethylation reaction of terminal alkenes occurs with high regioselectivity tolerating various functional groups including epoxides, nitro, ester, amine and hydroxyl groups.

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