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ChemInform Abstract: Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A C(sp3)—H Bond Activation α to the Trifluoromethyl Group.

✍ Scribed by Yong Guo; Xiaming Zhao; Dazhi Zhang; Shun-Ichi Murahashi

Publisher
John Wiley and Sons
Year
2009
Weight
30 KB
Volume
40
Category
Article
ISSN
0931-7597

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Iridium-Catalyzed Reactions of Trifluoro
Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A CH Bond Activation α to the Trifluoromethyl Group
✍ Yong Guo; Xiaming Zhao; Dazhi Zhang; Shun-Ichi Murahashi 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 293 KB

## Abstract **Catalytic convenience**: The use of iridium or ruthenium catalysts for CH bond activation has led to the addition reaction of trifluoromethylated compounds to alkenes (see scheme). This atom‐economical reaction occurs under neutral reaction conditions and without the formation of und