ChemInform Abstract: Convenient and Stereoselective Synthesis of (Z)-1-Bromo-1-alkenes by Microwave-Induced Reaction.
β Scribed by Chunxiang Kuang; Hisanori Senboku; Masao Tokuda
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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Stereoselective Hydrogenolysis of 1,1-Dibromo-1-alkenes and Stereospecific Synthesis of Conjugated (Z)-Alkenyl Compounds. -The Pd-catalyzed hydrogenolysis of 1,1-dibromo-1-alkenes with Bu 3 SnH proceeds stereoselectively yielding (Z)-1-bromo-1-alkenes. Alkenyl-and alkynylconjugated 1,1-dibromo-1-al