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ChemInform Abstract: Palladium-Catalyzed Stereoselective Hydrogenolysis of Conjugated 1,1- Dibromo-1-alkenes to (Z)-1-Bromo-1-alkenes. An Application to Stepwise and One-Pot Synthesis of Enediynes and Dienynes.

โœ Scribed by J. UENISHI; R. KAWAHAMA; O. YONEMITSU; J. TSUJI


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective Hyd
โœ Jun'ichi Uenishi; Reiko Kawahama; Osamu Yonemitsu; Jiro Tsuji ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 38 KB ๐Ÿ‘ 2 views

Stereoselective Hydrogenolysis of 1,1-Dibromo-1-alkenes and Stereospecific Synthesis of Conjugated (Z)-Alkenyl Compounds. -The Pd-catalyzed hydrogenolysis of 1,1-dibromo-1-alkenes with Bu 3 SnH proceeds stereoselectively yielding (Z)-1-bromo-1-alkenes. Alkenyl-and alkynylconjugated 1,1-dibromo-1-al