𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Stereoselective Hydrogenolysis of 1,1-Dibromo-1-alkenes and Stereospecific Synthesis of Conjugated (Z)-Alkenyl Compounds.

✍ Scribed by Jun'ichi Uenishi; Reiko Kawahama; Osamu Yonemitsu; Jiro Tsuji

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
30
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis

Stereoselective Hydrogenolysis of 1,1-Dibromo-1-alkenes and Stereospecific Synthesis of Conjugated (Z)-Alkenyl Compounds.

-The Pd-catalyzed hydrogenolysis of 1,1-dibromo-1-alkenes with Bu 3 SnH proceeds stereoselectively yielding (Z)-1-bromo-1-alkenes. Alkenyl-and alkynylconjugated 1,1-dibromo-1-alkenes also undergo stereoselective hydrogenolysis. The reaction of the 1,1-diiodoalkene (VI) gives a mixture of products, while 1,1-dichloro-1-alkenes do not react under these conditions.

Pd-catalyzed cross-couplings of 1,1-dibromo-1-alkenes and (Z)-1-bromo-1-alkenes provide polyenes or enynes bearing a (Z)-alkenyl unit in good yields. -(UENISHI, JUN'ICHI; KAWAHAMA, REIKO; YONEMITSU,

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Synthesis of 1,1-Di
ChemInform Abstract: Synthesis of 1,1-Dibromo-1-alkenes from Partially and Unprotected Aldoses.
✍ Franck Dolhem; Catherine Lievre; Gilles Demailly πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v