ChemInform Abstract: Control of the Regioselectivity in Palladium(0)-Catalyzed Allylic Alkylation
β Scribed by Stephanie Norsikian; Chih-Wei Chang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 15 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The chemoβ and regioselectivity in the Pdβcatalyzed allylic alkylation can be tuned by using bases with different counterions.
Remote Electronic Control of the Ligand in the Enantioselective Palladium-Catalyzed Allylic Alkylation with Chiral Oxazolinylpyridines. -New chiral oxazolinylpyridines (I) bearing electrondonating or electron-withdrawing groups at the 4-position of the pyridine are investigated as ligands in the Pd
Scheme 6. Asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate (8).