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Bulky Monodentate Phosphoramidites in Palladium-Catalyzed Allylic Alkylation Reactions: Aspects of Regioselectivity and Enantioselectivity

✍ Scribed by Maarten D. K. Boele; Paul C. J. Kamer; Martin Lutz; Anthony L. Spek; Johannes G. de Vries; Piet W. N. M. van Leeuwen; Gino P. F. van Strijdonck

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
441 KB
Volume
10
Category
Article
ISSN
0947-6539

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✦ Synopsis

Scheme 6. Asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate (8).

πŸ“œ SIMILAR VOLUMES

Cover Picture: Bulky Monodentate Phospho
Cover Picture: Bulky Monodentate Phosphoramidites in Palladium-Catalyzed Allylic Alkylation Reactions: Aspects of Regioselectivity and Enantioselectivity (Chem. Eur. J. 24/2004)
✍ Maarten D. K. Boele; Paul C. J. Kamer; Martin Lutz; Anthony L. Spek; Johannes G. πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 25 KB πŸ‘ 2 views

**The cover picture shows** a modeled structure (PM3(tm)‐level) of a TADDOL derived monoligated bulky phosphorus amidite palladium–allyl complex. The allyl fragment, shown in green, has the __syn__,__syn__ conformation and is clearly blocked by the aryl fragment of the __S__,__S__ ligand upon counte