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ChemInform Abstract: Remote Electronic Control of the Ligand in the Enantioselective Palladium-Catalyzed Allylic Alkylation with Chiral Oxazolinylpyridines.

✍ Scribed by Giorgio Chelucci; Sebastiano P. Deriu; Antonio Saba; Raffaela Valenti

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199939029

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✦ Synopsis

Remote Electronic Control of the Ligand in the Enantioselective Palladium-Catalyzed Allylic Alkylation with Chiral Oxazolinylpyridines.

-New chiral oxazolinylpyridines (I) bearing electrondonating or electron-withdrawing groups at the 4-position of the pyridine are investigated as ligands in the Pd-catalyzed allylic substitution of the propenyl acetate (II) with dimethyl malonate.

The electron-withdrawing chlorine strongly decreases the catalytic activity. -(CHELUCCI, GIORGIO; DERIU,

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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