ChemInform Abstract: Chiral Palladium-Pincer Complex Catalyzed Asymmetric Condensation of Sulfonimines and Isocyanoacetate.
β Scribed by Juhanes Aydin; Andreas Ryden; Kalman J. Szabo
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 38 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Palladiumβcatalyzed condensation reactions of sulfonimines with isocyanoacetate were performed using various PCP, SCS, SeCSe and NCN pincer complexes as catalysts. The reactions proceeded rapidly (2β h) at room temperature using only 1 molβ% pincer complex catalyst without any additives.
Asymmetric Reactions Catalyzed by Chiral Metal Complexes. Part 75. Chiral Palladium Complex-Catalyzed Synthesis of Optically Active Vinylchromane. -The synthesis of optically active vinylchromane (III), a useful chiral intermediate to tocopherol analogue drugs, by catalytic and asymmetric allylic s