ChemInform Abstract: Chemistry in the Ambient Field of the Alkaloid Epibatidine. Part 1. 2-(Het)aryl-substituted 7-Azabicyclo[2.2.1]heptane Systems.
β Scribed by A. OTTEN; J. C. NAMYSLO; M. STOERMER; D. E. KAUFMANN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
Chemistry in the Ambient Field of the Alkaloid Epibatidine. Part 2. Triphenylarsine as an Efficient Ligand in the Pd-Catalyzed Synthesis of Epibatidine and Analogues. -Triphenylarsine is found to be more efficient than triphenylphosphine in the Pd-catalyzed coupling of bicyclic alkenes (I) with pyr
A New [4 + 2] Cycloaddition Strategy for the Synthesis of N-Acyl-7-azabicyclo[2.2.1]heptan-2-ones: A Formal Synthesis of (Β±)-Epibatidine. -The title compound (VIII), an intermediate for the preparation of (Β±)-epibatidine, is prepared via Diels-Alder reaction of allenes with N-acylated pyrrole (II)