ChemInform Abstract: Catalytic Enantioselective Intermolecular Cycloaddition of Diazodiketoester-Derived Carbonyl Ylides with Indoles Using Chiral Dirhodium(II) Carboxylates.
β Scribed by Naoyuki Shimada; Tadashi Oohara; Janagiraman Krishnamurthi; Hisanori Nambu; Shunichi Hashimoto
- Book ID
- 112042477
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 40 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Enantioselective 1,3-dipolar cycloaddition of the ester-carbonyl ylides derived from methyl 2-(diazoacetyl)benzoate and 3-(diazoacetyl)-2-naphthoate with dipolarophiles has been eected with the aid of dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate], aording cycloadducts in up to 93% ee.