ChemInform Abstract: Catalytic and Supported Barton—McCombie Deoxygenation of Secondary Alcohols: A Clean Reaction.
✍ Scribed by Paul Boussaguet; Bernard Delmond; Gilles Dumartin; Michel Pereyre
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
## A Practical Modification of the Barton-McCombie Reaction and Radical O-to S-Rearrangement of Xanthates. -A novel method for the title reaction avoiding toxic or expensive reagents is presented. It is noteworthy that in benzene as solvent the O-to S-rearranged compound is the major product. -(
Phosphine-Boranes as Selective Reagents for the Radical Deoxygenation of a Hindered Secondary Alcohol. -Refluxing the carbohydrate derived xanthates (I) and (III) with phosphine-borane in the presence of catalytic AIBN provides an efficient procedure for deoxygenation. -(BARTON,
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