ChemInform Abstract: A Practical Modification of the Barton-McCombie Reaction and Radical O- to S-Rearrangement of Xanthates.

✍ Scribed by Beatrice Quiclet-Sire; Samir Z. Zard

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 29 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199911061

✦ Synopsis

A Practical Modification of the Barton-McCombie Reaction and

Radical O-to S-Rearrangement of Xanthates.

-A novel method for the title reaction avoiding toxic or expensive reagents is presented. It is noteworthy that in benzene as solvent the O-to S-rearranged compound is the major product.

-(QUICLET-SIRE, BEATRICE; ZARD, SAMIR Z.;