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ChemInform Abstract: Phosphine-Boranes as Selective Reagents for the Radical Deoxygenation of a Hindered Secondary Alcohol.

✍ Scribed by D. H. R. BARTON; M. JACOB


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Phosphine-Boranes as Selective Reagents for the Radical Deoxygenation of a Hindered Secondary Alcohol.

-Refluxing the carbohydrate derived xanthates (I) and (III) with phosphine-borane in the presence of catalytic AIBN provides an efficient procedure for deoxygenation. -(BARTON,


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