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ChemInform Abstract: Carbonyl Ylide Formation from the Rhodium-Catalyzed Reaction of α -Diazo Ketones

✍ Scribed by A. PADWA


Book ID
112039046
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
27
Category
Article
ISSN
0931-7597

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Cyclic carbonyl ylide formation from the
✍ Albert Padwa; Richard L. Chinn; Susan F. Hornbuckle; Lin Zhi 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 293 KB

Treatment of 1-diazoalkanediones with rhodium (II) acetate results in cyclization of the intermediate rhodium carbenoid to give a cyclic carbonyl ylide which readily undergoes bimolecular dipolar cycloaddition with various dipolarophiles. a-Diazoketones are valuable synthetic intermediates, with con