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Ruthenium(II) Porphyrin Catalyzed Tandem Carbonyl Ylide Formation and 1,3-Dipolar Cycloaddition Reactions of α-Diazo Ketones.

✍ Scribed by Cong-Ying Zhou; Wing-Yiu Yu; Chi-Ming Che


Publisher
John Wiley and Sons
Year
2003
Weight
261 KB
Volume
34
Category
Article
ISSN
0931-7597

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Catalytic Enantioselective Tandem Carbon
✍ Hideyuki Tsutsui; Naoyuki Shimada; Takumi Abe; Masahiro Anada; Makoto Nakajima; 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 2 views

## Abstract The first successful example of the enantioselective intermolecular 1,3‐dipolar cycloaddition of a chiral dirhodium(II) catalyst‐associated carbonyl ylide with an aromatic aldehyde dipolarophile is described. The tandem carbonyl ylide formation/cycloaddition reactions of 1‐diazo‐5‐aryl‐