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ChemInform Abstract: Rhodium(II)-Catalyzed Carbocyclization Reaction of α-Diazo Carbonyls with Tethered Unsaturation.

✍ Scribed by Albert Padwa; M. David Weingarten


Publisher
John Wiley and Sons
Year
2000
Weight
37 KB
Volume
31
Category
Article
ISSN
0931-7597

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The general title cyclization is demonstrated by alkylative (without PPh3) and reductive (with PPh3) cyclization methods. Considerable flexibility is tolerated in each of the reactive functionality. A proposed mechanism is discussed. -