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ChemInform Abstract: Carbonyl Propargylation by 1-Substituted Prop-2-ynyl Mesylates and Carbonyl Allenylation by 3-Substituted Prop-2-ynyl Mesylates with Tin(II) Iodide and Tetrabutylammonium Iodide.

✍ Scribed by Yoshiro Masuyama; Akiko Watabe; Akihiro Ito; Yasuhiko Kurusu

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200107038

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Carbonyl Propargylation and Allenylation

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ChemInform Abstract: Carbonyl Propargyla

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γ-syn-Selective Carbonyl Allylation by 1-Bromo-2-butene with Tin( II) Iodide and Tetrabutylammonium Bromide. -The first Barbier-type γ-syn-selective carbonyl allylation of aldehydes (II) by (E)-rich bromoalkene (I) in the presence of tin(II) iodide and tetrabutylammonium bromide (or iodide) is pres