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Carbonyl Allylations by 3-Halopropenes or 2-Propenyl Mesylate with Tin(IV) Chloride and Tetrabutylammonium Iodides.

โœ Scribed by Yoshiro Masuyama; Takanori Suga; Akiko Watabe; Yasuhiko Kurusu


Publisher
John Wiley and Sons
Year
2003
Weight
103 KB
Volume
34
Category
Article
ISSN
0931-7597

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ฮณ-syn-Selective Carbonyl Allylation by 1-Bromo-2-butene with Tin( II) Iodide and Tetrabutylammonium Bromide. -The first Barbier-type ฮณ-syn-selective carbonyl allylation of aldehydes (II) by (E)-rich bromoalkene (I) in the presence of tin(II) iodide and tetrabutylammonium bromide (or iodide) is pres