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ChemInform Abstract: Carbonyl Propargylation or Allenylation by 3-Haloprop-1-yne with Tin(II) Halides and Tetrabutylammonium Halides.

✍ Scribed by Y. MASUYAMA; A. ITO; M. FUKUZAWA; K. TERADA; Y. KURUSU

Publisher: John Wiley and Sons
Year: 2010
Weight: 34 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199902046

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ChemInform Abstract: γ-syn-Selective Carbonyl Allylation by 1-Bromo-2-butene with Tin( II) Iodide and Tetrabutylammonium Bromide.

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γ-syn-Selective Carbonyl Allylation by 1-Bromo-2-butene with Tin( II) Iodide and Tetrabutylammonium Bromide. -The first Barbier-type γ-syn-selective carbonyl allylation of aldehydes (II) by (E)-rich bromoalkene (I) in the presence of tin(II) iodide and tetrabutylammonium bromide (or iodide) is pres