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ChemInform Abstract: Asymmetric Total Synthesis of (-)-Epibatidine.

✍ Scribed by S. AOYAGI; R. TANAKA; M. NARUSE; C. KIBAYASHI

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: An Asymmetric Synth
ChemInform Abstract: An Asymmetric Synthesis (-)-Epibatidine.
✍ B. M. TROST; G. R. COOK πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 1 views

An Asymmetric Synthesis (-)-Epibatidine. -The title compound (X) is synthesized with a view to its biological activity and its low natural abundance. Key steps in this synthesis are the Pd-catalyzed desymmetrization of the dibenzoate (I) and the Pd-catalyzed cross coupling of the vinyl bromide (V)