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ChemInform Abstract: Asymmetric Synthesis of (+)- and (-)-Eptazocine via an Enzymatic Reaction.

โœ Scribed by S. SHIOTANI; H. OKADA; T. YAMAMOTO; K. NAKAMATA; J. ADACHI; H. NAKAMOTO

Book ID
112032131
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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โœ A. FADEL; P. ARZEL ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB

Enzymatic Asymmetrization of Prochiral ฮฑ,ฮฑ-Disubstituted-malonates and -1,3-propanediols: Formal Asymmetric Syntheses of (-)-Aphanorphine and (+)-Eptazocine. -A method for the synthesis of the title compounds (X) and (XIII) is presented with a view to their analgesic activity. Two key intermediates