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ChemInform Abstract: Asymmetric Synthesis of 1-Alkoxy-2,2,2-trifluoroethanol Derivatives.

✍ Scribed by H. PORAS; H. MATSUTANI; J. YARUVA; T. KUSUMOTO; T. HIYAMA

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199847043

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✦ Synopsis

Asymmetric Synthesis of 1-Alkoxy-2,2,2-trifluoroethanol Derivatives.

-The title compounds such as (IV) and (VI), which may be useful as chiral building blocks, are prepared via trapping the intermediately formed optically active hemiacetals. The substitution of isopropanol in the chiral complex against other alcohols gives only very similar or less effective catalysts. -(

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