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ChemInform Abstract: Asymmetric syn-Dihydroxylation of β-Substituted (2R)-N-(α,β-Enoyl)bornane-10,2-sultams.

✍ Scribed by J. RACZKO; M. ACHMATOWICZ; A. JEZEWSKI; C. CHAPUIS; Z. URBANCZYK-LIPKOWSKA; J. JURCZAK

Publisher: John Wiley and Sons
Year: 2010
Weight: 37 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199841183

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Asymmetric Simmons-Smith Cyclopropanation of α,β-Unsaturated Bornane-2,3-diol Acetals. -Reaction of selected α,β-unsaturated aldehydes (II) with bornanediol (I) affords novel chiral acetals (III), which undergo diastereoselective cyclopropanation with a Simmons-Smith reagent giving compounds (V). -

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