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ChemInform Abstract: Influence of Lewis Acids on the [4 + 2] Cycloaddition of N,N′-Fumaroylbis[(2R)-bornane-10,2-sultam] to Cyclopentadiene and Application to Various Dienes.

✍ Scribed by T. BAUER; C. CHAPUIS; A. KUCHARSKA; P. RZEPECKI; J. JURCZAK


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
29
Category
Article
ISSN
0931-7597

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Stereoselectivity in the TiCl4-Catalyzed
✍ Michal Achmatowicz; Christian Chapuis; Piotr Rzepecki; Janusz Jurczak 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 134 KB 👁 2 views

The [4 2] cycloaddition of cyclopentadiene to the (2R )-bornane-10,2-sultam derivative (À)-1b of fumaric monomethyl ester proceeds with high endo and p-facial diastereoselectivity in the presence of 0.5 mol-equiv. of TiCl 4 . The major diastereoisomer endo-(2R,3R )-2b, isolated in 87% yield by cryst