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ChemInform Abstract: Asymmetric Simmons—Smith Cyclopropanation of α,β-Unsaturated Bornane-2,3-diol Acetals.

✍ Scribed by Perry T. Kaye; Warner E. Molema

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Asymmetric Simmons-Smith Cyclopropanation of α,β-Unsaturated Bornane-2,3-diol Acetals.

-Reaction of selected α,β-unsaturated aldehydes (II) with bornanediol (I) affords novel chiral acetals (III), which undergo diastereoselective cyclopropanation with a Simmons-Smith reagent giving compounds (V). -(KAYE,

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