## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
ChemInform Abstract: Asymmetric Nitroaldol Reaction Catalyzed by a Chromium(III)—Salen System.
✍ Scribed by Rafal Kowalczyk; Lukasz Sidorowicz; Jacek Skarzewski
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 22 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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Asymmetric Hetero-Diels-Alder Reactions Catalyzed by Chiral (Salen)Chromium(III) Complexes. -The title reactions between (I) and a wide range of aldehydes require only 2 mol% of the catalyst and afford the pyranone derivatives (III) with good enantioselectivity. Among different derivatives of the c
## Abstract Aromatic as well as aliphatic aldehydes undergo the Henry reaction with nitromethane under catalysis of an in situ generated chiral amino alcohol—Zn complex to give the corresponding β‐nitroalcohols in moderate to good enantioselectivity.