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ChemInform Abstract: Asymmetric 1,4 Addition of Grignard Reagents to Chiral α,β- Unsaturated Imides in the Presence of Lewis Acids.

✍ Scribed by A. BONGINI; G. CARDILLO; A. MINGARDI; C. TOMASINI

Book ID
112038179
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES

ChemInform Abstract: Asymmetric 1,4 Addi
ChemInform Abstract: Asymmetric 1,4 Addition of Grignard Reagents to Chiral α,β-Unsaturated Esters in the Presence of Lewis Acids.
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Asymmetric 1,4 Addition of Grignard Reagents to Chiral α,β-Unsaturated Esters in the Presence of Lewis Acids. -The reaction proceeds with good yields but variable diastereoselectivities, depending on the organometallic reagent and Lewis acid used. -(CARDILLO, GIULIANA;

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The synthesis of enantiomerically enriched a-amino acids is described, by means of the diastereoselective conjugate addition of Grignard reagent to (S)-2-acetamidoacrylic ethoxycarbonylphenyl-methyl ester 1 and its N-Boo derivative 5 in the presence of Lewis acids. The addition of magnesium organocu

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✍ Pieter H. Bos; Adriaan J. Minnaard; Ben L. Feringa 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 41 KB 👁 2 views

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