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ChemInform Abstract: anti-Diastereo- and Enantioselective Carbonyl (Hydroxymethyl)allylation from the Alcohol or Aldehyde Oxidation Level: Allyl Carbonates as Allylmetal Surrogates.

โœ Scribed by Yong Jian Zhang; Jin Haek Yang; Sang Hoon Kim; Michael J. Krische


Publisher
John Wiley and Sons
Year
2010
Weight
55 KB
Volume
41
Category
Article
ISSN
0931-7597

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Iridium-Catalyzed anti-Diastereo-and Enantioselective Carbonyl (Trimethylsilyl)allylation from the Alcohol or Aldehyde Oxidation Level. -A highly anti-diastereo-and enantioselective (trimethylsilyl)allylation of aldehydes and alcohols is reported. Identical sets of products (III) are obtained with c