ChemInform Abstract: Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenation Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition.
β Scribed by In Su Kim; Ming-Yu Ngai; Michael J. Krische
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 56 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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Iridium-Catalyzed anti-Diastereo-and Enantioselective Carbonyl (Trimethylsilyl)allylation from the Alcohol or Aldehyde Oxidation Level. -A highly anti-diastereo-and enantioselective (trimethylsilyl)allylation of aldehydes and alcohols is reported. Identical sets of products (III) are obtained with c
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