ChemInform Abstract: Anionic Cyclizations of α-Aminoorganolithiums. Determination of the Stereoselectivity at the Carbanion Center and the Synthesis of (+)- Pseudoheliotridane.
✍ Scribed by I. COLDHAM; R. HUFTON; D. J. SNOWDEN
- Book ID
- 112037642
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Cyclization of Enantioenriched α-(Homoallyloxy)alkyllithiums: Evidence for Retention of Configuration at the Carbanion Center. -Carbanion cyclization of the title compounds derived from the corresponding stannanes (I) and (IV) under optimized conditions is shown to proceed with complete retention o
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