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ChemInform Abstract: Stereoselective Synthesis of α,α-Chlorofluoro Carbonyl Compounds Leading to the Construction of Fluorinated Chiral Quaternary Carbon Centers.

✍ Scribed by Kazutaka Shibatomi; Hisashi Yamamoto

Publisher
John Wiley and Sons
Year
2008
Weight
55 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Catalytic Enantiose
ChemInform Abstract: Catalytic Enantioselective Construction of β-Quaternary Carbons via a Conjugate Addition of Cyanide to β,β-Disubstituted α,β-Unsaturated Carbonyl Compounds.
✍ Yuta Tanaka; Motomu Kanai; Masakatsu Shibasaki 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 46 KB 👁 1 views

## Abstract A general catalytic enantioselective conjugate addition of cyanide to β,β‐disubstituted α,β‐unsaturated ketones and N‐acylpyrroles is developed using a strontium catalyst derived from Sr(OiPr)~2~ and a new chiral ligand.