ChemInform Abstract: An Expeditious Route to 3β,14β-Dihydroxy-5β-androstane- 17β-carboxaldehyde.
✍ Scribed by M. GOBBINI; M. TORRI
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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**Synthesis of 4‐[3β, 14‐Dihydroxy‐5β, 14β‐androstan‐17β‐yl]‐3‐pyrrolin‐2‐one (hothesimogenin)** We describe the synthesis of 4‐[3β, 14‐Dihydroxy‐5β, 14β‐androstan‐17β‐yl]‐3‐pyrrolin‐2‐one (24‐aza‐24‐desoxa‐digitoxigenin) **(7)**, starting from 3‐__O__‐acetyl‐digitoxigenin **(1)**.
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