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ChemInform Abstract: 3α,4β-Dihydroxy-5α-androstan-17-one.

✍ Scribed by J. A. PAIXAO; L. C. R. ANDRADE; M. J. DE ALMEIDA; M. M. R. R. COSTA; E. J. TAVAREES DA SILVA; M. L. SA E MELO; A. S. CAMPOS NEVES

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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Dissimilar behaviour of 3β, 16α-dihydrox
Dissimilar behaviour of 3β, 16α-dihydroxy-5α-androstan-17-one Diacetate under Basic and Acidic Conditions
✍ Darío Doller; Eduardo G. Gros 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 German ⚖ 333 KB

The base-catalysed rearrangement of 38,16a -dihydroxy-5a -androstan-17-one diacetate (1) in (D6)benzene/ CD,OD to 38,178-dihydroxy-5a -androstan-l6-one (3) is followed by I3C-NMR spectroscopy. By the same procedure, it is determined that in (D6)benzene/CD30D, but under acid catalysis, 1 does not rea