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ChemInform Abstract: An Expedient Synthesis of β-Chloro-β-nitroolefin Derivatives.

✍ Scribed by J. N. KIM; J. S. SON; H. J. LEE; K. S. JUNG


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


An Expedient Synthesis of β-Chloro-β-nitroolefin Derivatives.

-The title compounds (II) are prepared by chlorination of nitroolefins ( I) with HCl/DMF/Oxone system. Concerning the mechanism of the reaction addition of HOCl, generated from HCl and Oxone, to (I) followed by dehydration is proposed. -(KIM,


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