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ChemInform Abstract: Radical Cyclization of β-Alkoxymethacrylates: Expedient Synthesis of (+)-Methyl Nonactate.

✍ Scribed by Eun Lee; Seung Jib Choi

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A General and Stere
ChemInform Abstract: A General and Stereoselective Approach to Nonactate Esters and Isomers: A Versatile Synthesis of (+)-Methyl Nonactate.
✍ G. MANDVILLE; C. GIRARD; R. BLOCH 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 2 views

A General and Stereoselective Approach to Nonactate Esters and Isomers: A Versatile Synthesis of (+)-Methyl Nonactate. -The title compound (XIII), which is a subunit of the macrotetrolide antibiotic nonactin, is stereoselectively synthesized from the chiral hydroxyacetate (I) in 11 steps and 6.4% o