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ChemInform Abstract: An Effective Synthesis of N,N-Dimethylamides from Carboxylic Acids and a New Route from N,N-Dimethylamides to 1,2-Diaryl-1,2-diketones.

✍ Scribed by Takashi Kumagai; Tomohiro Anki; Takahiro Ebi; Akihito Konishi; Kouzou Matsumoto; Hiroyuki Kurata; Takashi Kubo; Kenta Katsumoto; Chitoshi Kitamura; Takeshi Kawase


Publisher
John Wiley and Sons
Year
2011
Weight
33 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Convenient Access
✍ C. PEROLLIER; J. PECAUT; R. RAMASSEUL; J.-C. MARCHON πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 2 views

A Convenient Access to N,N-Disubstituted Amides Derived from (1R,3S)-(-)-2,2-Dimethyl-3-formylcyclopropane-1-carboxylic Acid. -The enantiopure title amides are obtained in three steps from biocartol (I). Deprotection of the mono-N-substituted amides did not give the expected aldehydes such as (VII)