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ChemInform Abstract: An Asymmetric Synthesis of C-2-epi-Hygromycin A.

โœ Scribed by Barry M. Trost; Olivier Dirat; Joseph Dudash Jr.; Erik J. Hembre

Publisher
John Wiley and Sons
Year
2010
Weight
39 KB
Volume
33
Category
Article
ISSN
0931-7597

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A strategy for stereocontrolled syntheses of furanoside type of natural products is developed for a glycosyl aryl ether. This strategy resolves the issue of low diastereoselectivity typical of normal glycosidation methods for furanosides. All the stereochemistry ultimately derives from a desymmetriz