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ChemInform Abstract: Application of the AAA Reaction to the Synthesis of the Furanoside of C-2-epi-Hygromycin A: A Total Synthesis of C-2-epi-Hygromycin A.

✍ Scribed by Barry M. Trost; Joseph Dudash Jr.; Olivier Dirat

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200221190

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Application of the AAA Reaction to the S

Application of the AAA Reaction to the Synthesis of the Furanoside of C-2-epi-Hygromycin A: A Total Synthesis of C-2-epi-Hygromycin A

✍ Barry M. Trost; Joseph Dudash; Jr.; Olivier Dirat 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB 👁 2 views

A strategy for stereocontrolled syntheses of furanoside type of natural products is developed for a glycosyl aryl ether. This strategy resolves the issue of low diastereoselectivity typical of normal glycosidation methods for furanosides. All the stereochemistry ultimately derives from a desymmetriz

An Asymmetric Synthesis of C-2-epi-Hygro

An Asymmetric Synthesis of C-2-epi-Hygromycin A

✍ Barry M. Trost; Olivier Dirat; Joseph Dudash; Jr.; Erik J. Hembre 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 77 KB 👁 2 views

An Asymmetric Synthesis of C-2-epi-Hygro

An Asymmetric Synthesis of C-2-epi-Hygromycin A

✍ Barry M. Trost; Olivier Dirat; Joseph Dudash; Jr.; Erik J. Hembre 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 76 KB 👁 2 views

ChemInform Abstract: An Asymmetric Synth

ChemInform Abstract: An Asymmetric Synthesis of C-2-epi-Hygromycin A.

✍ Barry M. Trost; Olivier Dirat; Joseph Dudash Jr.; Erik J. Hembre 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 1 views

ChemInform Abstract: Asymmetric Inductio

ChemInform Abstract: Asymmetric Induction of Conduritols via AAA Reactions: Synthesis of the Aminocyclohexitol of Hygromycin A.

✍ Barry M. Trost; Joseph Dudash Jr.; Erik J. Hembre 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB 👁 1 views

Asymmetric Induction of Conduritols via

Asymmetric Induction of Conduritols via AAA Reactions: Synthesis of the Aminocyclohexitol of Hygromycin A

✍ Barry M. Trost; Joseph Dudash; Jr.; Erik J. Hembre 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 184 KB 👁 2 views

Two synthetic routes towards the construction of the aminocyclohexitol moiety of hygromycin A have been developed based on palladium-catalyzed asymmetric alkylation of conduritol derivatives. A protocol has been established whereby this biologically relevant molecule is formed from benzoquinone. A c