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ChemInform Abstract: Aerobic Oxidation of α-Hydroxycarbonyls Catalyzed by Trichlorooxyvanadium: Efficient Synthesis of α-Dicarbonyl Compounds.

✍ Scribed by Masayuki Kirihara; Yuta Ochiai; Shinobu Takizawa; Hiroki Takahata; Hideo Nemoto

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Aerobic Oxidation of α-Hydroxycarbonyls Catalyzed by Trichlorooxyvanadium: Efficient Synthesis of α-Dicarbonyl Compounds.

-Efficient and chemoselective aerobic oxidation of α-hydroxycarbonyls to αdicarbonyls is achieved using a catalytic amount of VOCl 3 under optimized conditions. It is noteworthy that this oxidation is not a radical reaction because it could not be influenced by 2,6-di(tert.-butyl)p-cresol. -(KIRI-

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