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ChemInform Abstract: Efficient Oxidation of 1,2-Diols into α-Hydroxyketones Catalyzed by Organotin Compounds.

✍ Scribed by Toshihide Maki; Shinya Iikawa; Gen Mogami; Hitomi Harasawa; Yoshihiro Matsumura; Osamu Onomura


Publisher
John Wiley and Sons
Year
2009
Weight
39 KB
Volume
40
Category
Article
ISSN
0931-7597

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Efficient Oxidation of 1,2-Diols into α-
✍ Toshihide Maki; Shinya Iikawa; Gen Mogami; Hitomi Harasawa; Yoshihiro Matsumura; 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 291 KB

## Abstract **Get selective!** A selective oxidation of 1,2‐diols to α‐hydroxyketones catalyzed by organotin compounds has been developed (see scheme). Invaluable chemo‐ and stereoselectivity were found in the reaction. The catalytic system has been achieved by electrochemical and chemical oxidatio

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Aerobic Oxidation of α-Hydroxycarbonyls Catalyzed by Trichlorooxyvanadium: Efficient Synthesis of α-Dicarbonyl Compounds. -Efficient and chemoselective aerobic oxidation of α-hydroxycarbonyls to αdicarbonyls is achieved using a catalytic amount of VOCl 3 under optimized conditions. It is noteworthy