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Ruthenium-Catalyzed Facile Aerobic Oxidation of α-Hydroxycarbonyls to 1,2-Dicarbonyl Compounds.

✍ Scribed by Sukbok Chang; Myunghee Lee; Sangwon Ko; Phil Ho Lee


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
33
Category
Article
ISSN
0931-7597

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Aerobic Oxidation of α-Hydroxycarbonyls Catalyzed by Trichlorooxyvanadium: Efficient Synthesis of α-Dicarbonyl Compounds. -Efficient and chemoselective aerobic oxidation of α-hydroxycarbonyls to αdicarbonyls is achieved using a catalytic amount of VOCl 3 under optimized conditions. It is noteworthy