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ChemInform Abstract: Additional Data on the Synthesis and Properties of Chiral 1,2-Bis(phosphetano)benzenes.

✍ Scribed by Angela Marinetti; Sebastien Jus; Jean-Pierre Genet; Louis Ricard

Book ID
101893997
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
31
Category
Article
ISSN
0931-7597

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Additional Data on the Synthesis and Pro
Additional Data on the Synthesis and Properties of Chiral 1,2-Bis(phosphetano)benzenes
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The synthesis of chiral, C 2 -symmetric 1,2-bis(phosphetano)benzenes 2 has been extended to the benzyl-substituted derivative 2c (RCH 2 Ph). Stable ruthenium and palladium complexes containing ligands 2 have been isolated. X-Ray diffraction studies have been performed on the monoborane adduct of 2a

ChemInform Abstract: Synthesis of Chiral
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## Synthesis of Chiral Azamacrocycles Using the Bis(Ξ±chloroacetamide)s Derived from Chiral 1,2-Diphenylethylenediamine. -Polyazamacrocycles such as (VIII) and (X) are prepared by reaction of the bis(Ξ±-chloroacetamide) (VI) with a number of polyamines. The optically pure starting compounds, e.g. (