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Additional Data on the Synthesis and Properties of Chiral 1,2-Bis(phosphetano)benzenes

✍ Scribed by Angela Marinetti; Sébastien Jus; Jean-Pierre Genêt; Louis Ricard

Book ID: 104209663
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 174 KB
Volume: 56
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(99)00777-2

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✦ Synopsis

The synthesis of chiral, C 2 -symmetric 1,2-bis(phosphetano)benzenes 2 has been extended to the benzyl-substituted derivative 2c (RCH 2 Ph). Stable ruthenium and palladium complexes containing ligands 2 have been isolated. X-Ray diffraction studies have been performed on the monoborane adduct of 2a (Ri-Pr) and on a palladium(II) complex of 2b (RMe).

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