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ChemInform Abstract: Acyclic Stereocontrol via Sequential and Tandem (2,3)-Wittig-Anionic Oxy-Cope Rearrangements.

โœ Scribed by N. GREEVES; K. J. VINES


Book ID
112021118
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
26
Category
Article
ISSN
0931-7597

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Stereoselective [2,3]-Wittig and Tandem
โœ Nicholas Greeves; Wai-Man Lee ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 589 KB

Acyclic bis-allylic ethers undergo,syn or anti stereoselective[2,3]-Wittig rearrangementto give homoallylic alcohols dependingon the substituents,and E-selective tandem [2,3]-Wittig-anionic oxy-Coperearrangementto give 8,&-unsaturated aldehydes. O 1997Elsevier ScienceLtd.